Portable EDXRF and Principal Component Analysis for inorganic element determination and provenance of eye shadows

Portable EDXRF and Principal Component Analysis for inorganic element determination and provenance of eye shadows

Authors

  • Rafael Molari Universidade Estadual de Londrina
  • Lucas Yoshimi Endo Universidade Estadual de Londrina
  • Carlos Roberto Appoloni Universidade Estadual de Londrina
  • Fábio Luiz Melquiades Universidade Estadual de Londrina
  • Otávio Portezan Filho Universidade Estadual de Londrina
  • Paulo Sergio Parreira Universidade Estadual de Londrina

DOI:

https://doi.org/10.5433/1679-0375.2019v40n2p135

Keywords:

EDXRF, Principal Component Analysis, Cosmetics..

Abstract

Nowadays cosmetic products play an important role in the life of almost all people. Men and women devote much time, resources and efforts to cultivate personal hygiene and the best possible look along their lives. One of the most widely used kind of cosmetics is eye shadow. X-ray fluorescence (XRF) is a well-established technique, known for its ability to identify and quantify inorganic species in a simple, fast and non-destructive way, however, it is not extensively used in cosmetic analysis. In order to show the potentiality of the technique, portable energy-dispersive X-ray fluorescence spectrometry has been employed in the quantification of inorganic elements in 40 Brazilian eye shadows. It was possible to identify and quantify the elements Cl, K, Ca, Ti, Cr, Mn, Fe, Cu, Zn and Bi. Using principal component analysis, specific manufacturers could be distinguished. The X-ray fluorescence methodology associated with principal component analysis proved to be a valuable tool for the discrimination and characterization of cosmetics.

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Author Biographies

Rafael Molari, Universidade Estadual de Londrina

Master in Physics from the State University of Londrina. PhD student in Physics at the State University of Londrina.

Lucas Yoshimi Endo, Universidade Estadual de Londrina

Doutor em Física pela Universidade Estadual de Londrina. Professor na Faculdade Pitágoras de Londrina

Carlos Roberto Appoloni, Universidade Estadual de Londrina

Post-Doctorate in Applied Nuclear Physics at the Universitá di Roma La Sapienza. Professor Londrina State University (UEL)

Fábio Luiz Melquiades, Universidade Estadual de Londrina

PhD in Physics from the State University of Londrina. Post doctorate at the Institute of Chemistry of UNICAMP. Professor at the State University of Londrina and member of the Master's and Doctorate Program in Physics of this institution.

Otávio Portezan Filho, Universidade Estadual de Londrina

PhD in Physics from the University of São Paulo. Associate Professor at the State University of Londrina.

Paulo Sergio Parreira, Universidade Estadual de Londrina

PhD in Science Nuclear Energy Concentration Area at Ag by the Center for Nuclear Energy in Agriculture. Assistant Professor at the State University of Londrina.

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Published

2019-12-18

How to Cite

Molari, R., Endo, L. Y., Appoloni, C. R., Melquiades, F. L., Portezan Filho, O., & Parreira, P. S. (2019). Portable EDXRF and Principal Component Analysis for inorganic element determination and provenance of eye shadows. Semina: Ciências Exatas E Tecnológicas, 40(2), 135–144. https://doi.org/10.5433/1679-0375.2019v40n2p135

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