Análise da estabilidade de dispositivos fotovoltaicos orgânicos através da eficiência quântica externa (EQE)
DOI:
https://doi.org/10.5433/1679-0375.2022v43n1p95Palavras-chave:
Eficiência quântica externa, Dispositivos fotovoltaicos, Materiais híbridos, Materiais orgânicosResumo
A utilização de painéis solares com a finalidade de converter energia solar em energia elétrica tem sido cada vez mais comum na comunidade, onde a grande maioria desses painéis é produzida a partir de materiais inorgânicos, principalmente o silício (Si). Nas últimas décadas, muitos pesquisadores vêm analisando materiais orgânicos e híbridos para aplicá-los em dispositivos fotovoltaicos. A utilização de materiais orgânicos e híbridos em dispositivos é vantajosa devido a alguns fatores, como: baixo custo de produção, variedade de materiais disponíveis, produção de dispositivos flexíveis. Uma análise fundamental para qualquer dispositivo fotovoltaico é a medida de eficiência quântica externa (EQE). Essa técnica correlaciona o número de fótons incidentes com o número de elétrons gerados, possibilitando saber em qual região do espectro eletromagnético o dispositivo fotovoltaico é mais eficiente. Este trabalho tem como objetivo aplicar a técnica de caracterização de eficiência quântica externa para a avaliação de diferentes tipos de dispositivos fotovoltaicos em termos de estabilidade.Métricas
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Referências
ALVES, J. P. D. C. Troca de ligantes em nanopartículas de PbS: influência sobre as propriedades fotofísicas, morfológicas e fotovoltaicas de filmes híbridos. [S. l.: s. n.], 2017.
BAI, F.; ZHANG, J.; ZENG, A.; ZHAO, H.; DUAN, K.; YU, H.; CHENG, K.; CHAI, G.; CHEN, Y.; LIANG, J.; MA, W.; YAN, H. A highly crystalline non-fullerene acceptor enabling efficient indoor organic photovoltaics with high EQE and fill factor. Joule, Cambridge, v. 5, n. 5, p. 1231-1245, 2021. DOI: https://doi.org/10.1016/j.joule.2021.03.020.
BARNES, P. R.; ANDERSON, A. Y.; KOOPS, S. E.; DURRANT, J. R.; O’REGAN, B. C. Electron injection efficiency and diffusion length in dye-sensitized solar cells derived from incident photon conversion efficiency measurements. The Journal of Physical Chemistry C, Washington, v. 113, n. 3, p. 1126-1136, 2009. DOI: https://doi.org/10.1021/jp809046j.
BRISTOW, N. Outdoor stability studies in Organic Photovoltaics. Thesis (Doctor of Philosophy) - Bangor University, United Kingdom, 2017.
BONDARENKO, E. A.; STRELTSOV, E. A.; MAZANIK, A. V.; KULAK, A. I.; GRIVICKAS, V.; SCAJEV, P.; SKORB, E. V. Bismuth oxysulfide film electrodes with giant incident photon-to-current conversion efficiency: the dynamics of properties with deposition time. Physical Chemistry Chemical Physics, Cambridge, v. 20, n. 31, p.~20340-20346, 2018.
BRINKMANN, K. O.; BECKER, T.; ZIMMERMANN, F.; KREUSEL, C.; GAHLMANN, T.; HAEGER, T.; RIEDL, T. The optical origin of near-unity external quantum efficiencies in perovskite solar cells. Solar RRL, Weinheim, v. 5, n. 9, p. 2100371, 2021.
CHAKRABORTY, I.; BODURTHA, K. J.; HEEDER, N. J.; GODFRIN, M. P.; TRIPATHI, A.; HURT, R. H.; SHUKLA, A.; BOSE, A. Massive electrical conductivity enhancement of multilayer graphene/polystyrene composites using a nonconductive filler. ACS applied materials & interfaces, Washington, v. 6, n. 19, p. 16472-16475, 2014.
CHANDER, N.; SINGH, S.; IYER, S. S. K. Stability and reliability of P3HT: PC61BM inverted organic solar cells. Solar Energy Materials and Solar Cells, Amsterdam, v.~161, p. 407-415, 2017.
CHANG, S.-W.; WATERS, H.; KETTLE, J.; KUO, Z.-R.; LI, C.-H.; YU, C.-C.; HORIE, M. Pd-Catalysed Direct Arylation Polymerisation for Synthesis of Low-Bandgap Conjugated Polymers and Photovoltaic Performance. Macromolecular rapid communications, Basel, v. 33, n. 22, p. 1927-1932, 2012. DOI: https://doi.org/10.1002/marc.201200368.
COATES, N. E.; HWANG, I.-W.; PEET, J.; BAZAN, G. C.; MOSES, D.; HEEGER, A. J. 1, 8-octanedithiol as a processing additive for bulk heterojunction materials: Enhanced photoconductive response. Applied Physics Letters, New York, v. 93, n. 7, p. 072105-1-072105-3, 2008. DOI: https://doi.org/10.1063/1.2969405.
GAO, J.; GAO, W.; MA, X.; HU, Z.;XU, C.; WANG, X.; AN, Q.; YANG, C.; ZHANG, X.; ZHANG, F. Over 14.5\% efficiency and 71.6% fill factor of ternary organic solar cells with 300 nm thick active layers. Energy & Environmental Science, Cambridge, v. 13, n. 3, p. 958-967, 2020.
HORIE, M.; MAJEWSKI, L. A.; FEARN, M. J.; YU, C.-Y.; LUO, Y.; SONG, A.; SAUNDERS, B. R.; TURNER, M. L. Cyclopentadithiophene based polymers—a comparison of optical, electrochemical and organic field-effect transistor characteristics. Journal of Materials Chemistry, Cambridge, v. 20, n. 21, p. 4347-4355, 2010.
HU, Z.; WANG, J.; MA, X.; GAO, J.; XU, C.; YANG, K.; WANG, Z.; ZHANG, J.; ZHANG, F. A critical review on semitransparent organic solar cells. Nano Energy, Amsterdam, v. 78, p. 105376, 2020.
JIANG, B.-H.; LEE, H.-E.; LU, J.-H.; TSAI, T.-H. SHIEH, T.-S; JENG, R. -J.; CHEN, C,-P. High-performance semitransparent organic photovoltaics featuring a surface phase-matched transmission-enhancing Ag/ITO electrode. ACS Applied Materials & Interfaces, Washington, v. 12, n.~35, p. 39496-39504, 2020. DOI: https://pubs.acs.org/doi/10.1021/acsami.0c10906.
KETTLE, J.; HORIE, M.; MAJEWSKI, L.; SAUNDERS, B.; TULADHAR, S.; NELSON, J.; TURNER, M. L. Optimisation of PCPDTBT solar cells using polymer synthesis with Suzuki coupling. Solar Energy Materials and Solar Cells, Amsterdam, v. 95, n. 8, p. 2186-2193, 2011.
KETTLE, J.; WATERS, H.; HORIE, M.; CHANG, S. Effect of hole transporting layers on the performance of PCPDTBT: PCBM organic solar cells. Journal of Physics D: Applied Physics, London, v. 45, n. 12, p. 125102, 2012.
KETTLE, J.; WATERS, H.; DING, Z.; HORIE, M.; SMITH, G. C. Chemical changes in PCPDTBT:PCBM solar cells using XPS and TOF-SIMS and use of inverted device structure for improving lifetime performance. Solar Energy Materials and Solar Cells, Amsterdam, v. 141, p. 139-147, 2015.
KLEEBE, H. J.; TURQUAT, C.; SORARÙ, G. D. Phase separation in an SiCO glass studied by transmission electron microscopy and electron energy-loss spectroscopy. Journal of the American Ceramic Society, Westerville, v. 84, n. 5, p. 1073-1080, 2001.
LI, C.; WU, H.; ZHU, L.; XIAO, J.; LUO, Y.; LI, D.; MENG, Q. Study on negative incident photon-to-electron conversion efficiency of quantum dot-sensitized solar cells. Review of Scientific Instruments, Woodbury, v. 85, n. 2, p. 023103, 2014.
QIAN, M.; MAO, X.; WU, M.; CAO, Z.; LUI, Q.; SUN, L.; GAO, Y.; XUAN, X.; PAN, Y.; NIU, Y.; GONG, S. POSS polyimide sealed flexible triple-junction gaas thinfilm solar cells for space applications. Advanced Materials Technologies, Hoboken, v. 6, n. 12, p. 2100603, 2021.
REESE, M. O. et al. Consensus stability testing protocols for organic photovoltaic materials and devices. Solar Energy Materials and Solar Cells, Amsterdam, v. 95, n. 5, p. 1253-1267, 2011.
TAI, Q.; YAN, F. Emerging semitransparent solar cells: materials and device design. Advanced Materials, Weinheim, v. 29, n. 34, p. 1700192, 2017.
TROMHOLT, T.; MANCEAU, M.; HELGESEN, M.; CARLE, J. E.; KREBS, F. C. Degradation of semiconducting polymers by concentrated sunlight. Solar Energy Materials and Solar Cells, Amsterdam, v. 95, n. 5, p.~1308-1314, 2011.
WATERS, H.; BRISTOW, N.; MOUDAM, O.; CHANG, S.-W.; SU, C. -J.; WU, W. -R.; JENG, U. -S.; HORIE, M.; KETTLE, J. Effect of processing additive 1, 8-octanedithiol on the lifetime of PCPDTBT based Organic Photovoltaics. Organic Electronics, Amsterdam, v. 15, n.~10, p. 2433-2438, 2014.
XIONG, J.; XU, J.; JIANG, Y.; XIAO, Z.; BAO, Q.; HAO, F.; FENG, Y.; ZHANG, B.; JIN, Z.; DING, L. Fused-ring bislactone building blocks for polymer donors. Science bulletin, Amsterdam, v. 65, p. 1792, 2020.
YAN, L.; YI, J.; CHEN, Q.; DOU, J.; YANG, Y.; LIU, X.; CHEN, L.; MA, C. -Q. External load-dependent degradation of P3HT: PC 61 BM solar cells: behavior, mechanism, and method of suppression. Journal of Materials Chemistry A, Cambridge, v. 5, n. 20, p. 10010-10020, 2017.
ZHANG, M.; YE, M.; WANG, W.; MA, C.; WANG, S.; LIU, Q.; LIAN, T.; HUAMG, J.; LIN, Z. Synergistic Cascade Carrier Extraction via Dual Interfacial Positioning of Ambipolar Black Phosphorene for High-Efficiency Perovskite Solar Cells. Advanced Materials, Weinheim, v. 32, n. 28, p. 2000999, 2020
BAI, F.; ZHANG, J.; ZENG, A.; ZHAO, H.; DUAN, K.; YU, H.; CHENG, K.; CHAI, G.; CHEN, Y.; LIANG, J.; MA, W.; YAN, H. A highly crystalline non-fullerene acceptor enabling efficient indoor organic photovoltaics with high EQE and fill factor. Joule, Cambridge, v. 5, n. 5, p. 1231-1245, 2021. DOI: https://doi.org/10.1016/j.joule.2021.03.020.
BARNES, P. R.; ANDERSON, A. Y.; KOOPS, S. E.; DURRANT, J. R.; O’REGAN, B. C. Electron injection efficiency and diffusion length in dye-sensitized solar cells derived from incident photon conversion efficiency measurements. The Journal of Physical Chemistry C, Washington, v. 113, n. 3, p. 1126-1136, 2009. DOI: https://doi.org/10.1021/jp809046j.
BRISTOW, N. Outdoor stability studies in Organic Photovoltaics. Thesis (Doctor of Philosophy) - Bangor University, United Kingdom, 2017.
BONDARENKO, E. A.; STRELTSOV, E. A.; MAZANIK, A. V.; KULAK, A. I.; GRIVICKAS, V.; SCAJEV, P.; SKORB, E. V. Bismuth oxysulfide film electrodes with giant incident photon-to-current conversion efficiency: the dynamics of properties with deposition time. Physical Chemistry Chemical Physics, Cambridge, v. 20, n. 31, p.~20340-20346, 2018.
BRINKMANN, K. O.; BECKER, T.; ZIMMERMANN, F.; KREUSEL, C.; GAHLMANN, T.; HAEGER, T.; RIEDL, T. The optical origin of near-unity external quantum efficiencies in perovskite solar cells. Solar RRL, Weinheim, v. 5, n. 9, p. 2100371, 2021.
CHAKRABORTY, I.; BODURTHA, K. J.; HEEDER, N. J.; GODFRIN, M. P.; TRIPATHI, A.; HURT, R. H.; SHUKLA, A.; BOSE, A. Massive electrical conductivity enhancement of multilayer graphene/polystyrene composites using a nonconductive filler. ACS applied materials & interfaces, Washington, v. 6, n. 19, p. 16472-16475, 2014.
CHANDER, N.; SINGH, S.; IYER, S. S. K. Stability and reliability of P3HT: PC61BM inverted organic solar cells. Solar Energy Materials and Solar Cells, Amsterdam, v.~161, p. 407-415, 2017.
CHANG, S.-W.; WATERS, H.; KETTLE, J.; KUO, Z.-R.; LI, C.-H.; YU, C.-C.; HORIE, M. Pd-Catalysed Direct Arylation Polymerisation for Synthesis of Low-Bandgap Conjugated Polymers and Photovoltaic Performance. Macromolecular rapid communications, Basel, v. 33, n. 22, p. 1927-1932, 2012. DOI: https://doi.org/10.1002/marc.201200368.
COATES, N. E.; HWANG, I.-W.; PEET, J.; BAZAN, G. C.; MOSES, D.; HEEGER, A. J. 1, 8-octanedithiol as a processing additive for bulk heterojunction materials: Enhanced photoconductive response. Applied Physics Letters, New York, v. 93, n. 7, p. 072105-1-072105-3, 2008. DOI: https://doi.org/10.1063/1.2969405.
GAO, J.; GAO, W.; MA, X.; HU, Z.;XU, C.; WANG, X.; AN, Q.; YANG, C.; ZHANG, X.; ZHANG, F. Over 14.5\% efficiency and 71.6% fill factor of ternary organic solar cells with 300 nm thick active layers. Energy & Environmental Science, Cambridge, v. 13, n. 3, p. 958-967, 2020.
HORIE, M.; MAJEWSKI, L. A.; FEARN, M. J.; YU, C.-Y.; LUO, Y.; SONG, A.; SAUNDERS, B. R.; TURNER, M. L. Cyclopentadithiophene based polymers—a comparison of optical, electrochemical and organic field-effect transistor characteristics. Journal of Materials Chemistry, Cambridge, v. 20, n. 21, p. 4347-4355, 2010.
HU, Z.; WANG, J.; MA, X.; GAO, J.; XU, C.; YANG, K.; WANG, Z.; ZHANG, J.; ZHANG, F. A critical review on semitransparent organic solar cells. Nano Energy, Amsterdam, v. 78, p. 105376, 2020.
JIANG, B.-H.; LEE, H.-E.; LU, J.-H.; TSAI, T.-H. SHIEH, T.-S; JENG, R. -J.; CHEN, C,-P. High-performance semitransparent organic photovoltaics featuring a surface phase-matched transmission-enhancing Ag/ITO electrode. ACS Applied Materials & Interfaces, Washington, v. 12, n.~35, p. 39496-39504, 2020. DOI: https://pubs.acs.org/doi/10.1021/acsami.0c10906.
KETTLE, J.; HORIE, M.; MAJEWSKI, L.; SAUNDERS, B.; TULADHAR, S.; NELSON, J.; TURNER, M. L. Optimisation of PCPDTBT solar cells using polymer synthesis with Suzuki coupling. Solar Energy Materials and Solar Cells, Amsterdam, v. 95, n. 8, p. 2186-2193, 2011.
KETTLE, J.; WATERS, H.; HORIE, M.; CHANG, S. Effect of hole transporting layers on the performance of PCPDTBT: PCBM organic solar cells. Journal of Physics D: Applied Physics, London, v. 45, n. 12, p. 125102, 2012.
KETTLE, J.; WATERS, H.; DING, Z.; HORIE, M.; SMITH, G. C. Chemical changes in PCPDTBT:PCBM solar cells using XPS and TOF-SIMS and use of inverted device structure for improving lifetime performance. Solar Energy Materials and Solar Cells, Amsterdam, v. 141, p. 139-147, 2015.
KLEEBE, H. J.; TURQUAT, C.; SORARÙ, G. D. Phase separation in an SiCO glass studied by transmission electron microscopy and electron energy-loss spectroscopy. Journal of the American Ceramic Society, Westerville, v. 84, n. 5, p. 1073-1080, 2001.
LI, C.; WU, H.; ZHU, L.; XIAO, J.; LUO, Y.; LI, D.; MENG, Q. Study on negative incident photon-to-electron conversion efficiency of quantum dot-sensitized solar cells. Review of Scientific Instruments, Woodbury, v. 85, n. 2, p. 023103, 2014.
QIAN, M.; MAO, X.; WU, M.; CAO, Z.; LUI, Q.; SUN, L.; GAO, Y.; XUAN, X.; PAN, Y.; NIU, Y.; GONG, S. POSS polyimide sealed flexible triple-junction gaas thinfilm solar cells for space applications. Advanced Materials Technologies, Hoboken, v. 6, n. 12, p. 2100603, 2021.
REESE, M. O. et al. Consensus stability testing protocols for organic photovoltaic materials and devices. Solar Energy Materials and Solar Cells, Amsterdam, v. 95, n. 5, p. 1253-1267, 2011.
TAI, Q.; YAN, F. Emerging semitransparent solar cells: materials and device design. Advanced Materials, Weinheim, v. 29, n. 34, p. 1700192, 2017.
TROMHOLT, T.; MANCEAU, M.; HELGESEN, M.; CARLE, J. E.; KREBS, F. C. Degradation of semiconducting polymers by concentrated sunlight. Solar Energy Materials and Solar Cells, Amsterdam, v. 95, n. 5, p.~1308-1314, 2011.
WATERS, H.; BRISTOW, N.; MOUDAM, O.; CHANG, S.-W.; SU, C. -J.; WU, W. -R.; JENG, U. -S.; HORIE, M.; KETTLE, J. Effect of processing additive 1, 8-octanedithiol on the lifetime of PCPDTBT based Organic Photovoltaics. Organic Electronics, Amsterdam, v. 15, n.~10, p. 2433-2438, 2014.
XIONG, J.; XU, J.; JIANG, Y.; XIAO, Z.; BAO, Q.; HAO, F.; FENG, Y.; ZHANG, B.; JIN, Z.; DING, L. Fused-ring bislactone building blocks for polymer donors. Science bulletin, Amsterdam, v. 65, p. 1792, 2020.
YAN, L.; YI, J.; CHEN, Q.; DOU, J.; YANG, Y.; LIU, X.; CHEN, L.; MA, C. -Q. External load-dependent degradation of P3HT: PC 61 BM solar cells: behavior, mechanism, and method of suppression. Journal of Materials Chemistry A, Cambridge, v. 5, n. 20, p. 10010-10020, 2017.
ZHANG, M.; YE, M.; WANG, W.; MA, C.; WANG, S.; LIU, Q.; LIAN, T.; HUAMG, J.; LIN, Z. Synergistic Cascade Carrier Extraction via Dual Interfacial Positioning of Ambipolar Black Phosphorene for High-Efficiency Perovskite Solar Cells. Advanced Materials, Weinheim, v. 32, n. 28, p. 2000999, 2020
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2022-06-27
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Fernandes, R. V., Bristow, N., Toginho Filho, D. de O., Silva, O. H. M. da, & Laureto, E. (2022). Análise da estabilidade de dispositivos fotovoltaicos orgânicos através da eficiência quântica externa (EQE). Semina: Ciências Exatas E Tecnológicas, 43(1), 95–101. https://doi.org/10.5433/1679-0375.2022v43n1p95
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